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中南大学化工院易小艺教授成果托管

中南大学化工院易小艺教授成果托管

易小艺，教授，硕士生导师。
 
学习与工作经历：
1994.9-1998.6         天津科技大学 食品与工程系，本科
1998.9-2000.6         湖南长沙LG曙光电子有限公司，工程师
2000.9-2003.6         南京大学化学化工学院配位化学国家重点实验室，硕士
2003.9-2007.4         香港科技大学 化学系，博士
2007.4-2010.4         香港科技大学 化学系，博士后
2010.4-2011.11        中南大学 化学化工学院，副教授
2011.12-现在          中南大学 化学化工学院，教授，化学系副主任
 
 

研究方向：
● Molecular synthetic inorganic and organometallic chemistry
● High oxidation state metal complexes
● Transition metal complexes with metal-ligand multiple bonds
 
Our research is focused on investigation of new reactions and development
of innovative synthetic and characterization methodologies (particularly in
structural chemistry). The research interests are in the field of synthetic
inorganic and organometallic chemistry, current research projects include:
 
Synthesis and reactivity of the metal-nitrogen multiple bonds in
the high oxidation-state ruthenium complexes
We synthesized and characterized a series of ruthenium complexes with
ruthenium-nitrogen multiple bond containing an oxygen tripodal ligand, and
explored steric effect and electronic effect of substituents of ligands for
the stability and reactivity of these complexes, and studied the reactivity
of ruthenium-nitrogen multiple bonds with organic substrates. We reported
the formation of dinuclear imido complex from the reaction of a
ruthenium(VI) nitride with a ruthenium(II) hydride.


 
 
 
Synthesis and reactivity of the M(IV) (M = Ti, Zr, Ce) complexes
with oxygen donor ligand
a. Aqueous chemistry of M(IV) (M = Ti, Zr, Ce) complexes
We reported the synthesis of M(IV) (M = Ti, Zr, Ce) complexes with chelating
oxygen ligands that may serve as models for metal aqua ions and metal oxide
surfaces. Ti(IV) and Zr(IV) triflato and sulfato compounds are synthesized.
Hydrolysis of these triflato compounds in aqua media leads to mono-, di-,
tri- or tetranuclear group 4 oxo and hydroxo compounds. The interconversion
between these polynuclear Zr(IV) compounds are directed by pH value.



 
 
b. Metal-oxo anions as catalyst activated by Lewis-acid 
M=O group in meta oxo anions MOxy- is activated by high oxidation state
metal compounds LnM’ due to LnM’ as a lewis acid coordination with metal
oxo anions to form LnM’-O-M=O. Some novel structures of these compounds
are characterized by single crystal X-ray diffraction. The activated MOxy-
can catalytically undergo oxo transfer to the sulfide and alkane at room
temperature.

 


High-oxidation state Rh and Ir organometallic complexes and C-H
bond activation



We synthesized a series of Rh and Ir complexes [M(dtbpy)(R)]. Heating
condition results in intramolecular C-H activation of the neophyl ligand,
and cationic Ir and Rh alkyl complexes containing the non-coordinating
counteranion are capable of catalyzing the H/D exchange of THF using
D2O as the deuterium source.
 
Ruthenium phosphonate complexes and their magnetic properties



Ruthenium phosphonate compounds with a mixed valent diruthenium paddlewheel
core are synthesized. Template and pH value directed assembly of diruthenium
diphosphonates with different topologies and oxidation states. Magnetic
properties of diruthenium compounds are studied.
 
 
 
研究项目：
5. “镉米”中 Cd(II) 配位化学环境的探索研究，中国博士后科学基金， 2011-2012
4. “镉米”形成过程镉的形态特征和迁移机理，中南大学博士后基金， 2011-2012
3. 高氧化态钌-氮多重键配合物合成及反应研究，国家自然科学基金项目， 2011-2013
2. 含氧基配体高价态钌－氮多重键化合物合成及其反应性研究，中央高校基本科研业
   务费-青年教师助推课题（2010-2012）
1. 钌-氮多重键化合物，中南大学“猎英计划”（2010-2015）
 
参加学术会议：

9. 中国化学会第28届学术年会，成都（2012）
8. 中国化学会第八届全国无机化学会议，哈尔滨（2011）
7. 第四届全国多酸化学学术研讨会，通辽（口头报告，2011）
6. 11th Conference on Solid State Chemistry and Inorganic Synthesis joint
   with 2nd Dalton Trans. International Symposium, Shanghai (oral, 2010)
5. 2nd Asian Coordination Chemistry Conference, Nanjing (poster, 2009)
4. 6th National Conference on Coordination Chemistry (& International
   Symposium on Coordination Chemistry), Hong Kong (poster, 2009)
3. 37th International Conference on Coordination Chemistry, South Africa
   (poster, 2006)
2. International Symposium on Catalysis and Fine Chemicals 2004 (C & FC
   2004), Hong Kong (poster, 2004)
1. The Sixth Conference of the Asian Crystallographic Association, Hong Kong
   (poster, 2004)
商品编号：中南大学易小艺教授
商品型号：中南大学易小艺教授
人　气：247

标　签：中南大学化工院易小艺教授成果托管
商品介绍
论文发表：

31. Recent developments in ruthenium nitrido complexes,

X.Y. Yi, Y. Liang, C. Li, RSC Adv., 2013, 3, 3477-3486.

30. Heteropolymetallic complexes containing ReO4-: catalytic oxidation of sulfide,

C. Li, X. Peng, S.C. Zhang, L.Y. Chai, X.Y. Yi, Inorg. Chim. Acta, 2013, Doi:j.ica.
2012.12.020.

29. Catena-Poly [[[diaquanickel(II)-m-pyrazine-2-caboxylato-silver(I)-m-pyrazine-2-
carboxylato]nitrate dihydrate],

M. Yang, L.Y. Chai, X.Y. Yi, Acta Cryst., 2012, 68, 689.

28. Ruthenium(VI) nitrido complexes with a sterically bulky bidentate Schiff base
ligand,

H.Y. Ng, N.M. Lam, M. Yang, X.Y. Yi, I.D. Williams, W.H. Leung, Inorg. Chim. Acta,
2012, 394, 171-175.

27. Dinuclear ruthenium nitrido complexes supported by an oxygen tripodal ligand,

X.Y. Yi, H.Y. Ng, W.M. Cheung, H.H.Y. Sung, I.D. Williams, W.H. Leung, Inorg.
Chem., 2012, 51, 10529-10523.

 

26. Synthesis and Structure of a Bismuth(III)/Chromium(VI) Oxo Cluster Containing a
Bi4Cr4O12 Core,

G.C. Wang, X.Y. Yi, I.D. Williams, W.H. Leung, Inorg. Chem.,2011, 50, 9141-9146.

 

25. Synthesis, structures and reactivity of ruthenium nitrosyl complexes containing
Kläui's oxygen tripodal ligand,

H.F. Ip, X.Y. Yi, W.Y. Wong, I.D. Williams, W.H. Leung, Dalton Trans., 2011, 40,
11043-11050.

 

24. Ruthenium carbene complexes containing bidentate and tridentate P=O ligands,

W.M. Cheung, X.Y. Yi, G.C. Wang, I.D. Williams, W.H. Leung, J. organomet.
Chem., 2011, 696, 4007-4010.

 

23. Formation of a dinuclear imido complex from the reaction of a ruthenium(VI)
nitride with a ruthenium(II) hydride,

X.Y. Yi, H.Y. Ng, I.D. Williams, W.H. Leung, Inorg. Chem., 2011, 50, 1161-1163.


22. Anti-degradation of a recombinant complex protein by incorporation in small
molecular hydrogels,

H.M. Wang, Z. Wang, X.Y. Yi, J.F. Long, J.F. Liu, Z.M. Yang, Chem. Commun.,
2011, 47, 955-957.


21. Syntheses, structures, and reactivity of ruthenium(II) hydrido complexes
containing Kläui’s oxygen tripodal ligand,

X.Y. Yi, H.Y.N. G, C.S. Lai, I.D. Williams, W.H. Leung, Sci. China Chem., 2010, 53,
2139-2143.


20. Hydrolysis of Bis(p-nitrophenyl)phosphate with Tetravalent Metal Complexes
Containing Kläui’s Oxygen Tripodal Ligand,

X.Y. Yi, T.C.H. Lam, I.D. Williams, W.H. Leung, Inorg. Chem., 2010, 49, 2232–2238.


19. Heterometallic Ti/M (M = Ru, Re) Sulfato Complexes Containing the Kläui
Tripodal Ligand: Structural Model for Sulfated Metal Oxide-Supported Catalyst,

X.Y. Yi, H.H.Y. Sung, Q.F. Zhang, I.D. Williams, W.H. Leung, Dalton Trans., 2010,
39, 5737-5741.


18. C–H Activation with Iridium(III) and Rhodium(III) Alkyl Complexes Containing a
2,2’-Bipyridyl Ligand,

X.Y. Yi, K.W. Chan, E.K. Huang, Y.K. Sau, I.D. Williams, W.H. Leung, Eur. J. Inorg.
Chem., 2010, 2369-2375.


17. Insertion of Nitrene and Chalcogenolate Groups Into the Ir-C Bond in a
Cyclometalated Iridium(III) Complex,

Y.K. Sau, X.Y. Yi, K.W. Chan, C.S. Chan, I.D. Williams, W.H. Leung, J. organomet.
Chem., 2010, 695, 1399-1404.


16. Formation of a Ruthenium(II) Dicyclohexyl(h2-cyclohex-3-enyl)phosphine Hydride
Complex from an Alkylidene Precursor,

W.M. Cheung, W.H. Chiu, X.Y. Yi, Q.F. Zhang, I.D. Williams, W.H. Leung,  
Organometallics, 2010, 29, 1981-1984.


2010年以前发表论文：


15. Synthesis and Structures of Zirconium(IV) Hydrogensulfato and Carboxylato
Complexes with Kläui’s Oxygen Tripodal Ligand,

X.Y. Yi, Q.F. Zhang, I.D. Williams, W.H. Leung, J. organomet. Chem., 2009, 694,
4256-4260.


14. Ruthenium(VI) and Osmium(VI) Nitrido Complexes with Halogenated Phenolato
and Thiophenolato Ligands,

N.M. Lam, X.Y. Yi, W.M. Cheung, Q.F. Zhang, I.D. Williams, W.H. Leung, Inorg.
Chim. Acta., 2009, 362, 5190-5194.


13. Cerium(IV)-containing oxomolybdenum cluster with a unique Ce6Mo9O38 core
structure,

X.Y. Yi, H.H.Y. Sung, I.D. Williams, W.H. Leung Chem. Commun., 2008, 3269-3271.


12. Electrophilic Ruthenium (VI) Nitrido Complexes Containing Kläui’s Oxygen
Tripodal Ligand,

X.Y. Yi, T.C.H. Lam, Y.K. Sau, Q.F. Zhang, I.D. Williams, W.H. Leung, Inorg. Chem.,
2007, 46, 7193-7198.


11. Recent developments in the coordination and organometallic chemistry of Kläui’s
oxygen tripodal ligands,

W.H. Leung, Q.F. Zhang, X.Y. Yi, Coord. Chem. Rev., 2007, 251, 2266-2279.


10. Phosphato, Chromato, and Perrhenato Complexes of Titanium(IV) and Zirconium
(IV) Containing Kläui’s Tripodal Ligand

X.Y. Yi, Q.F. Zhang, I.D. Williams, W.H. Leung, Inorg. Chem., 2006, 45, 328-335.


9. Template- and pH-Directed Assembly of Diruthenium Diphosphonates with
Different Topologies and Oxidation States,

B. Liu, P. Yin, X.Y. Yi, S. Gao, L.M. Zheng, Inorg. Chem., 2006, 45, 4205-4213.


8. Titanium(IV) Terminal Hydroxo Complexes Containing Chelating Bis(phosphine
oxide) Ligands,

X.Y. Yi, I.D. Williams, W.H. Leung J. organomet. Chem., 2006, 691, 1315-1319.


7. Titanium and Vanadium Complexes with Tetraphenylimidodiphosphinate,

X.Y. Yi, K.Y. Ng, I.D. Williams, W.H. Leung, Inorg. Chim. Acta., 2006, 359, 3581-
3588.


6. Syntheses, Structures, and Magnetic Properties of Mixed-Valent Diruthenium(II,III)
Diphosphonates with Discrete and One-Dimensional Structures,

X.Y. Yi, B. Liu, R. Jiménez-Aparicio, F.A. Urbanos, S. Gao, W. Xu, J.S. Chen, Y. Song
L.M. Zheng, Inorg. Chem., 2005, 44, 4309-4314.


5. Titanium(IV) and Zirconium(IV) Sulfato Complexes Containing the Kläui Tripodal
Ligand: Molecular Models of Sulfated Metal Oxide Surfaces,

Q.F. Zhang, T.C.H. Lam, X.Y. Yi, I.D. Williams, W.H. Leung, Chem. Eur. J., 2005,
11, 101-111.


4. Novel Layered Ruthenium Diphosphonate Containing a Mixed Valent Diruthenium
Paddlewheel Core,

X.Y. Yi, L.M. Zheng, W. Xu, S. Feng, Inorg. Chem., 2003, 42, 2827-2829.


3. {M(C5H4N)CH(OH)PO3}(H2O) (M = Mn, Fe, Co): Layered Compounds Based on
[hydroxy(4-pyridyl)methyl] phosphonate,

X.Y. Yi, L.M. Zheng, W. Xu, J.S. Chen, Dalton Trans., 2003, 953-956.


2. Syntheses and characterization of one-dimensional antimony(III) diphosphonates:
[NH3(CH2)nNH3][Sb{CH3C(O)(PO3)2}] (n=4, 5),

X.Y. Yi, L.M. Zheng, J. Solid State Chem., 2002, 168, 263–266.


1.  [Hydroxy(4-pyridyl)methyl]phosphonic Acid Monohydrate,

X.Y. Yi, Y.Z. Li, L.M. Zheng, Acta Cryst., 2002, 58, 820-821.

 

 

 

 

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